Super-material poised to transform electronics landscape

July 14, 2009

Since its discovery just a few years ago, graphene has climbed to the top of the heap of new super-materials poised to transform the electronics and nanotechnology landscape.

As N.J. Tao, a researcher at the Biodesign Institute of Arizona State University explains, this two dimensional honeycomb structure of carbon atoms is exceptionally strong and versatile. Its unusual properties make it ideal for applications that are pushing the existing limits of microchips, chemical sensing instruments, biosensors, ultracapacitance devices, flexible displays and other innovations. Download Full Image

In the latest issue of Nature Nanotechnology, Tao describes the first direct measurement of a fundamental property of graphene, known as quantum capacitance, using an electrochemical gate method. A better understanding of this crucial variable should prove invaluable to other investigators participating in what amounts to a gold rush of graphene research.

Although theoretical work on single atomic layer graphene-like structures has been going on for decades, the discovery of real graphene came as a shock.

"When they found it was a stable material at room temperature," Tao says, "everyone was surprised."

As it happens, minute traces of graphene are shed whenever a pencil line is drawn, though producing a 2-D sheet of the material has proven trickier. Graphene is remarkable in terms of thinness and resiliency. A one-atom thick graphene sheet sufficient in size to cover a football field, would weigh less than a gram. It is also the strongest material in nature – roughly 200 times the strength of steel. Most of the excitement however, has to do with the unusual electronic properties of the material.

Graphene displays outstanding electron transport, permitting electricity to flow rapidly and more or less unimpeded through the material. In fact, electrons have been shown to behave as massless particles similar to photons, zipping across a graphene layer without scattering. This property is critical for many device applications and has prompted speculation that graphene could eventually supplant silicon as the substance of choice for computer chips, offering the prospect of ultrafast computers operating at terahertz speeds, rocketing past current gigahertz chip technology.

Yet, despite encouraging progress, a thorough understanding of graphene's electronic properties has remained elusive. Tao stresses that quantum capacitance measurements are an essential part of this understanding.

Capacitance is a material's ability to store energy. In classical physics, capacitance is limited by the repulsion of like electrical charges, for example, electrons. The more charge you put into a device, the more energy you have to expend to contain it, in order to overcome charge repulsion.

However, another kind of capacitance exists, and dominates overall capacitance in a two-dimensional material like graphene. This quantum capacitance is the result of the Pauli exclusion principle, which states that two fermions – a class of common particles including protons, neutrons and electrons – cannot occupy the same location at the same time. Once a quantum state is filled, subsequent fermions are forced to occupy successively higher energy states.

As Tao explains, "it's just like in a building, where people are forced to go to the second floor once the first level is occupied."

In the current study, two electrodes were attached to graphene, and a voltage applied across the material's two-dimensional surface by means of a third, gate electrode. In Tao's experiments, graphene's ability to store charge according to the laws of quantum capacitance, were subjected to detailed measurement.

The results show that graphene's capacitance is very small. Further, the quantum capacitance of graphene did not precisely duplicate theoretical predictions for the behavior of ideal graphene. This is due to the fact that charged impurities occur in experimental samples of graphene, which alter the behavior relative to what is expected according to theory.

Tao stresses the importance of these charged impurities and what they may mean for the development of graphene devices. Such impurities were already known to affect electron mobility in graphene, though their effect on quantum capacitance has only now been revealed. Low capacitance is particularly desirable for chemical sensing devices and biosensors as it produces a lower signal-to-noise ratio, providing for extremely fine-tuned resolution of chemical or biological agents.

Improvements to graphene will allow its electrical behavior to more closely approximate theory. This can be accomplished by adding counter ions to balance the charges resulting from impurities, thereby further lowering capacitance.

The sensitivity of graphene's single atomic layer geometry and low capacitance promise a significant boost for biosensor applications. Such applications are a central topic of interest for Tao, who directs the Biodesign Institute's Center for Bioelectronics and Biosensors.

As Tao explains, any biological substance that interacts with graphene's single atom surface layer can be detected, causing a huge change in the properties of the electrons.

One possible biosensor application under consideration would involve functionalizing graphene's surface with antibodies, in order to precisely study their interaction with specific antigens. Such graphene-based biosensors could detect individual binding events, given a suitable sample. For other applications, adding impurities to graphene could raise overall interfacial capacitance. Ultracapacitors made of graphene composites would be capable of storing much larger amounts of renewable energy from solar, wind or wave energy than current technologies permit.

Because of graphene's planar geometry, it may be more compatible with conventional electronic devices than other materials, including the much-vaunted carbon nanotubes.

"You can imagine an atomic sheet, cut into different shapes to create different device properties," Tao says.

Since the discovery of graphene, the hunt has been on for similar two-dimensional crystal lattices, though so far, graphene remains a precious oddity.

Richard Harth,">
The Biodesign Institute Media contact:

Joe Caspermeyer

Manager (natural sciences), Media Relations & Strategic Communications


Partnership brings ASU teaching degrees to Pinal County

July 14, 2009

Residents of Pinal County who aspire to careers as special education and elementary education teachers now have a convenient path to a bachelor’s degree and Arizona certification, thanks to a cooperative program between" target="_blank">Central Arizona College and Arizona State University.

The program enables students to turn their two-year associate’s degree from CAC into a Bachelor of Arts in Education degree and dual teacher certification in elementary and special education through" target="_blank">ASU’s College of Teacher Education and Leadership (CTEL) without leaving Pinal County. Download Full Image

“CTEL classes are delivered online and via teleconference to CAC’s campuses and centers,” says Holly Aguila, Title V Grant director for CTEL. “Students are placed in Pinal County elementary and middle school classrooms for their field experience and student teaching. The hope is that the school districts in which students conduct their field work will hire them once they graduate, as there is a great need for highly qualified special education teachers in Pinal County.”

“This is a classic win-win situation,” says Jenni Gonzales, CAC’s co-director for Title V, who helped develop the partnership. “Both ASU and CAC bring expertise in teacher preparation to the program. At CAC we have the technical infrastructure to make interactive television classes available at all nine of our campuses and centers, and ASU provides a high-quality bachelor’s degree program that leads to teacher certification.

“The ultimate winners are the college students who can become certified teachers without facing a long commute, and the children in Pinal County schools who will benefit from the talented teachers this program produces.”

Aguila says the fact that the program leads to two teaching certificates makes it especially appealing. “Graduates meet the Arizona requirements to receive both elementary and special education certification, providing them greater flexibility in their career options,” she says.

Once students have completed an associate’s degree, they can complete the ASU portion of the program in two academic years. During the first three semesters they take online and videoconference classes while also doing field work in Pinal County classrooms under the guidance of experienced mentor teachers. The fourth and final semester is spent student teaching.

Evening teleconference classes are offered at various locations around the county as well as at CAC’s Signal Peak, Superstition Mountain and Aravaipa campuses.

Applications are now being accepted for students planning to enter the program in the Fall 2009 semester (with classes starting Aug. 24). Potential students can reach a program representative by calling (480) 727-1103 or emailing teachinpinal">"> Additional information is available at


ASU’s College of Teacher Education and Leadership, through collaboration with educational and civic communities, prepares and inspires innovative educators to be leaders who apply evidence-based knowledge that positively impacts students, families, and the community. CTEL offers teacher preparation programs on all ASU campuses.