New material can enhance energy, computer, lighting technologies


November 15, 2011

Crystal erbium compound offers superior optical properties

Arizona State University researchers have created a new compound crystal material that promises to help produce advances in a range of scientific and technological pursuits. Erbium crystal structure Download Full Image

Cun-Zheng Ning, an electrical engineering professor at ASU, says the material, called erbium chloride silicate, can be used to develop the next generations of computers, improve the capabilities of the Internet, increase the efficiency of silicon-based photovoltaic cells to convert sunlight into electrical energy, and enhance the quality of solid-state lighting and sensor technology.

Ning’s research team of team of students and post-doctoral degree assistants help synthesize the new compound in ASU’s Nanophotonics Lab in the School of Electrical, Computer and Energy Engineering, one of the university’s Ira A. Fulton Schools of Engineering.

The lab’s erbium research is supported by the U.S.  Army Research Office and U.S. Air Force Office of Scientific Research.  Details about the new compound are reported in the Optical Materials Express on the website of the Optical Society of America.

The breakthrough involves the first-ever synthesis of a new erbium compound in the form of a single-crystal nanowire, which has superior properties compared to erbium compounds in other forms.

 Erbium is one of the most important members of the rare earth family in the periodic table of chemical elements. It emits photons in the wavelength range of 1.5 micrometers, which are used in the optical fibers essential to high-quality performance of the Internet and telephones.

Erbium is used in doping optical fibers to amplify the signal of the Internet and telephones in telecommunications systems. Doping is the term used to describe the process of inserting low concentrations of various elements into other substances as a way to alter the electrical or optical properties of the substances to produce desired results. The elements used in such processes are referred to as dopants.

“Since we could not dope as many erbium atoms in a fiber as we wish, fibers had to be very long to be useful for amplifying an Internet signal. This makes integrating Internet communications and computing on a chip very difficult,” Ning explains.

“With the new erbium compound, 1,000 times more erbium atoms are contained in the compound. This means many devices can be integrated into a chip-scale system,” he says. “Thus the new compound materials containing erbium can be integrated with silicon to combine computing and communication functionalities on the same inexpensive silicon platform to increase the speed of computing and Internet operation at the same time.”
 
Erbium materials can also be used to increase the energy-conversion efficiency of silicon solar cells.

Silicon does not absorb solar radiation with wavelengths longer than 1.1 microns, which results in waste of energy – making solar cells less efficient.

Erbium materials can remedy the situation by converting two or more photons carrying small amounts of energy into one photon that is carrying a larger amount of energy. The single, more powerful photon can then be absorbed by silicon, thus increasing the efficiency of solar cells.

Erbium materials also help absorb ultraviolet light from the sun and convert it into photons carrying small amounts of energy, which can then be more efficiently converted into electricity by silicon cells.  This color-conversion function of turning ultraviolet light into other visible colors of light is also important in generating white light for solid-state lighting devices.

While erbium’s importance is well-recognized, producing erbium materials of high quality has been challenging, Ning says.

The standard approach is to introduce erbium as a dopant into various host materials, such as silicon oxide, silicon, and many other crystals and glasses.

“One big problem has been that we have not been able to introduce enough erbium atoms into crystals and glasses without degrading optical quality, because too many of these kinds of dopants would cluster, which lowers the optical quality,” he says.

What is unique about the new erbium material synthesized by Ning’s group is that erbium is no longer randomly introduced as a dopant. Instead, erbium is part of a uniform compound and the number of erbium atoms is a factor of 1,000 more than the maximum amount that can be introduced in other erbium-doped materials.

Increasing the number of erbium atoms provides more optical activity to produce stronger lighting. It also enhances the conversion of different colors of light into white light to produce higher-quality solid-state lighting and enables solar cells to more efficiently convert sunlight in electrical energy.
 
In addition, since erbium atoms are organized in a periodic array, they do not cluster in this new compound.  The fact that the material has been produced in a high-quality single-crystal form makes the optical quality superior to the other doped materials, Ning says.
 
Like many scientific discoveries, the synthesis of this new erbium material was made somewhat by accident.

“Similar to what other researchers are   doing, we were originally trying to dope erbium into silicon nanowires. But the characteristics demonstrated by the material surprised us,” he says. “We got a new material. We did not know what it was, and there was no published document that described it. It took us more than a year to finally realize we got a new single-crystal material no one else had produced.”  

Ning and his team are now trying to use the new erbium compound for various applications, such as increasing silicon solar cell efficiency and making miniaturized optical amplifiers for chip-scale photonic systems for computers and high-speed Internet.

“Most importantly,” he says, “there are many things we have yet to learn about what can be achieved with use of the material. Our preliminary studies of its characteristics show it has many amazing properties and superior optical quality. More exciting discoveries are waiting to be made.”

Learn more about Ning's nanophotonics group.

 

Joe Kullman

Science writer, Ira A. Fulton Schools of Engineering

480-965-8122

Engineers aim to make technology work better in extreme environs


November 15, 2011

It’s what the experts call “hostile-environment technology.” These are the machines, devices and various mechanisms made to perform tasks in places that are dangerous or impossible for humans to tread. Like in outer space, on other planets or inside nuclear reactor facilities.

Two Arizona State University electrical engineers are leading research to aid in developing the next generation of these technologies, supported by a recent $1.7 million grant from the Defense Threat Reduction Agency of the U.S. Department of Defense. electrical and materials testing facility Download Full Image

Hugh Barnaby, associate professor, and Michael Kozicki, professor, in the School of Electrical, Computer and Energy Engineering, one of ASU’s Ira A. Fulton Schools of Engineering, are working to help ensure new versions of the technologies will be more resilient and perform more effectively in environments with high levels of radiation and extreme hot and frigid temperatures.

Specifically, their focus is on specialized materials that are used in components of very small and low-power integrated circuits in electronic sensors and communications systems designed to process, store and wirelessly transmit information from hostile environments.

They will get help on aspects of the project from fellow ASU electrical engineering professor Keith Holbert and former ASU research scientist Maria Mitkova, now an associate professor at Boise State University in Idaho.

The specialized materials involved are chalcogenide glasses, which are compounds formed from such elements as sulfur and selenium.  What makes these compounds particularly useful is that they change physical and electrical properties when electronic signals are used to redistribute metal atoms within their nano-structured interiors.

"This mechanism of physical change, which is much more stable than the control of electrical charge used in conventional electronics, will help the material better withstand high radiation and extreme environments,” Kozicki says.

He’s been working for many years on nano-ionic technologies, including development of chalcogenide-based commercial memory devices for use in computers, hand-held electronic devices and other consumer electronics.
 
Chalcogenide glasses are already widely used. They’re in rewritable DVDs, infrared detectors, lenses and optical fibers.  Kozicki says electronic memory devices containing these materials should be in the marketplace next year.
 
Barnaby specializes in developing advanced systems to enable information collected in harsh environments to be accurately measured and reliably transmitted to people safely removed – sometimes at vast distances – from the danger zones.

Holbert will contribute to the project by producing models of precisely how radiation is absorbed in chalcogenide materials. Holbert directs the Radiation Damage Laboratory at ASU, where materials can be tested for how they are affected by radiation.

Mitkova , also an expert in chalcogenide glass systems, will provide studies of radiation-induced changes in the properties of materials and related devices.

The work is part of larger efforts to provide the nation with enhanced exploration technologies, more reliable public-safety systems and stronger defense systems.
 

Joe Kullman

Science writer, Ira A. Fulton Schools of Engineering

480-965-8122